A layered semiconductor, SrTiN2, has an attention-grabbing crystal construction as a two-dimensional (2D) electron system embedded in a three-dimensional bulk periodic construction as a result of it has alternate stacking of a SrN blocking layer and a TiN conduction layer, by which the Ti 3dxy orbital types the conduction band minimal (CBM) just like the SrTiO3-based thin-film heterostructure.
Nevertheless, SrTiN2 has been reported to exhibit almost degenerate conduction, however we reported that it could be because of the simple formation of nitrogen vacancies and oxygen impurities from air. On this paper, we lengthen the supplies to household compounds, alkaline earth (AE) ion-substituted, AETiN2 (AE = Ca, Sr, and Ba), and investigated how we will suppress the defect formation by (hybrid) density useful principle calculations.
All AETiN2 compounds possess thermodynamic stability within the broad nitrogen (N) chemical potential window. Particularly, CaTiN2 is probably the most steady even towards N-poor circumstances. Unintentional service technology happens because of the nitrogen vacancies (VN), oxygen substitution (ON), and hydrogen anion substitution (HN) on the nitrogen websites. The VN and HN impurities may be suppressed below N-moderate and N-rich circumstances.
The ON defect is well shaped in SrTiN2 and in addition in BaTiN2 below N-rich circumstances, however its formation may be suppressed in CaTiN2. Current outcomes counsel that high-purity CaTiN2 may be obtained below wider N chemical circumstances, which might result in the conclusion of the novel useful properties originating from Ti 3dxy 2D bands embedded within the bulk crystal construction.
Realizing cool and heat white-LEDs based mostly on coloration controllable (Sr,Ba) 2 Al 3 O 6 F:Eu 2+ phosphors obtained through a microwave-assisted diffusion methodology
Globally, phosphor transformed white-LEDs (W-LEDs) are among the many most fitted sources to cut back vitality consumption. Nonetheless, modernization of environment friendly broadband emitting phosphors is most vital to enhance the W-LED efficiency. Herein, we synthesized a collection of novel broadband emitting Sr2-xAl3O6F:xEu2+ phosphors through a brand new microwave-assisted diffusion methodology. Rietveld refinement of the obtained X-ray diffraction outcomes was carried out to acknowledge the precise crystal section and the assorted cationic websites.
Oxygen vacancies (VO) shaped below artificial lowering circumstances enabled Sr2Al3O6F to show vibrant self-activated bluish emission. Doping of Eu2+ ions unlocked the vitality switch course of from the host to the activator ions, owing to which, the self-activated emission diminished and the Eu2+-doped pattern confirmed amplified bluish-green emission.
The gradual improve in Eu2+ concentrations regulated the controllable emissions from the bluish (0.34, 0.42) to the greenish (0.38, 0.43) zone below UV excitation. Due to the totally different absorption preferences of Eu2+ ions positioned on the totally different Sr2+ websites, Sr2-xAl3O6F:xEu2+ exhibited bluish-white emission below blue irradiation. An additional enhancement in PL depth had been noticed by the cation substitution of Ba2+ for Sr2+ websites within the optimum Sr1.95Al3O6F:0.05Eu2+ phosphor.

The as-fabricated W-LEDs using the optimized Sr1.75Ba0.2Al3O6F:0.05Eu2+ phosphor exhibited a cool-white mild emission together with a 372 nm NUV-LED and a 420 nm blue-LED with a average CRI of 70 and a CCT above 6000 Ok. Such cool white emission was managed to pure white with the CCT near 5000 Ok, and the CRI above 80 through using an appropriate purple emitting phosphor. The W-LED performances of the optimized phosphor justified its applicability to supply white mild for lighting purposes.
Wilhelm His Sr. and the event of paraffin embedding
Paraffin histology is likely one of the most vital and commonly-used laboratory strategies in diagnostic histopathology. The invention of paraffin embedding is usually attributed to the pathologist Edwin Klebs. Klebs was following the lead of Stricker, who embedded embryos in a mix of sizzling stearin and white beeswax. We present that Klebs experimented with paraffin wax for embedding tumour tissue. However he shortly rejected it as unsuitable as a result of paraffin wax didn’t infiltrate the tissue.
Considered one of Klebs’ correspondents, embryologist Wilhelm His, Sr., discovered of Klebs’ experiments and determined to strive paraffin embedding. His dehydrated rooster embryos in alcohol, cleared them in lavender oil, and dripped sizzling paraffin wax onto them. This course of allowed His to chop good sections. Right here, we’ve replicated His’s paraffin embedding protocol with the intention to decide whether or not His had certainly made the landmark discovery of infiltration embedding with paraffin wax.
We adopted the protocol that he provides in his 1868 monograph on the early improvement of the rooster. The protocol described by His failed, in our arms, to yield sections of the standard that he illustrates in his monograph. Usually, the tissue disintegrated when sectioned because of poor infiltration of the wax. Usable sections may solely be obtained if His’s protocol was modified by melting the embedded embryos in contemporary paraffin wax.
Chemical phosphorylation amidite, 250 mg |
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22560 | Lumiprobe | 250 mg | EUR 193 |
Human Probetacellulin [Cleaved into: Betacellulin protein (BTC) |
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1-CSB-EP002853HU | Cusabio |
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Description: Recombinant Human Probetacellulin [Cleaved into: Betacellulin protein(BTC) expressed in E.coli |
Chemical Phosphorylation Reagent I (CPR I) |
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6001 | AAT Bioquest | 1 g | EUR 480 |
Exosome-TEM-easy Kit |
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P130 | 101Bio | - | Ask for price |
EXOCET Exosome Quantitation Kit |
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EXOCET96A-1 | SBI | 96 reactions | EUR 521 |
FluoroCet Exosome Quantitation Kit |
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FCET96A-1 | SBI | 96 reactions | EUR 726 |
Exosome Isolation kit (for serum & plasma -Exosome-RNA-NGS) |
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P101NGS | 101Bio | - | Ask for price |
Frit Kit |
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FRIT-KIT | Next Advance | 1each | EUR 124 |
Description: Kit to create frits in capillaries. Includes formamide, Kasil-1, Kasil-1624 and a cleaving tool. |
Psoriasis Exosome |
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P141-PS | 101Bio | - | Ask for price |
Column Packing Kit |
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PACK-KIT | Next Advance | 1pack | EUR 1035 |
Description: Column packing kit for pressure cells. Includes: HPREG regulator, TBNG10 tubing, CAP-75 capillary, and STRB5X2 stir bar. |
Into growth factor β 3 (TGF β 3) ELISA Kit |
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QY-E120019 | Qayee Biotechnology | 96T | EUR 478 |
Into growth factor β 31(TGF β 1) ELISA Kit |
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QY-E120020 | Qayee Biotechnology | 96T | EUR 478 |
PCR Mycoplasma Detection Kit |
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M034-Kit | TOKU-E | Kit | EUR 266 |
pC003 - LshC2C2 locus into pACYC184 for spacer cloning |
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PVT10647 | Lifescience Market | 2 ug | EUR 301 |
Chemical Defined Xeno-free Cell Cryopreservation Medium |
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abx298009-20ml | Abbexa | 20 ml | EUR 244 |
Cas9 Protein and T7 gRNA SmartNuclease Synthesis Kit |
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CAS400A-KIT | SBI | 1 kit (10 rxn) | EUR 1110 |
Exosome Isolation kit (for urine) |
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P120 | 101Bio | - | Ask for price |
Exosome Isolation kit (for urine) |
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P120L | 101Bio | - | Ask for price |
Exosome Isolation kit (for urine) |
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P120S | 101Bio | - | Ask for price |
Exo-Fect Exosome Transfection Kit |
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EXFT10A-1 | SBI | 10 reactions | EUR 293 |
Exo-Fect Exosome Transfection Kit |
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EXFT20A-1 | SBI | 20 reactions | EUR 489 |
LiqBiopsy Tumor Exosome RNA Kit |
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K1254-24 | Biovision | EUR 1110 |
SeraMir Exosome RNA Ampflication Kit |
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RA800A-1 | SBI | 20 reactions | EUR 914 |
CMV-hspCas9-T2A-Puro SmartNuclease Lentivector Plasmid + LentiStarter Packaging Kit |
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CASLV100PA-KIT | SBI | 1 Kit | EUR 1132 |
CMV-hspCas9-EF1-GFP SmartNuclease Lentivector Plasmid + LentiStarter Packaging Kit |
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CASLV105PA-KIT | SBI | 1 Kit | EUR 1132 |
MSCV-hspCas9-T2A-Puro SmartNuclease Lentivector Plasmid + LentiStarter Packaging Kit |
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CASLV120PA-KIT | SBI | 1 Kit | EUR 1132 |
MSCV-hspCas9-EF1-GFP SmartNuclease Lentivector Plasmid + LentiStarter Packaging Kit |
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CASLV125PA-KIT | SBI | 1 Kit | EUR 1132 |
Multiplex gRNA Kit + EF1-T7-hspCas9-H1-gRNA linearized SmartNuclease vector |
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CAS700A-KIT | SBI | 10 rxn | EUR 1132 |
Multiplex gRNA Kit + CAG-T7-hspCas9-H1-gRNA linearized SmartNuclease vector |
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CAS720A-KIT | SBI | 10 rxn | EUR 1132 |
Multiplex gRNA Kit + CMV-T7-hspCas9-H1-gRNA linearized SmartNuclease vector |
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CAS740A-KIT | SBI | 10 rxn | EUR 1132 |
T7 gRNA SmartNuclease Synthesis Kit (includes CAS510A-1 & T7 IVT synthesis reagents) |
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CAS510A-KIT | SBI | 1 Kit | EUR 805 |
Leukemia - ALL Exosome |
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P141-ALL | 101Bio | - | Ask for price |
Leukemia - AML Exosome |
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P141-AML | 101Bio | - | Ask for price |
Bladder Cancer Exosome |
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P141-BL | 101Bio | - | Ask for price |
Breast Cancer Exosome |
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P141-BR | 101Bio | - | Ask for price |
Leukemia - CLL Exosome |
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P141-CLL | 101Bio | - | Ask for price |
Leukemia - CML Exosome |
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P141-CML | 101Bio | - | Ask for price |
Colorectal Cancer Exosome |
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P141-CO | 101Bio | - | Ask for price |
Crohn's Disease Exosome |
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P141-CR | 101Bio | - | Ask for price |
Kidney Cancer Exosome |
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P141-KN | 101Bio | - | Ask for price |
Lung Cancer Exosome |
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P141-LG | 101Bio | - | Ask for price |
Liver Cancer Exosome |
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P141-LV | 101Bio | - | Ask for price |
Nasopharyngeal Cancer Exosome |
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P141-NA | 101Bio | - | Ask for price |
Prostate Cancer Exosome |
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P141-PR | 101Bio | - | Ask for price |
Rheumatoid Arthritis Exosome |
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P141-RA | 101Bio | - | Ask for price |
Thyroid Cancer Exosome |
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P141-TH | 101Bio | - | Ask for price |
Psoriasis Exosome RNA |
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P241-PS | 101Bio | - | Ask for price |
Exosome precipitation Solution |
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EPStep | ImmunoStep | 12 ml | EUR 277.5 |
Lyophilized Exosome Standards |
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ExoA375 | ImmunoStep | 100 μg | EUR 303.5 |
Lyophilized Exosome Standards |
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ExoHT29 | ImmunoStep | 100 μg | EUR 303.5 |
Lyophilized Exosome Standards |
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ExoMCF7 | ImmunoStep | 100 μg | EUR 303.5 |
Lyophilized Exosome Standards |
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ExoPC3 | ImmunoStep | 100 μg | EUR 303.5 |
Lyophilized Exosome Standards |
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ExoPLASMA | ImmunoStep | 100 μg | EUR 303.5 |
Lyophilized Exosome Standards |
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ExoUrine | ImmunoStep | 100 μg | EUR 303.5 |
Cas9 Nickase: CMV-hspCas9(D10A)-T2A-Puro SmartNickase Lentivector Plasmid + LentiStarter Packaging Kit |
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CASLV200PA-KIT | SBI | 1 Kit | EUR 1132 |
Cas9 Nickase: CMV-hspCas9(D10A)-EF1-GFP SmartNickase Lentivector Plasmid + LentiStarter Packaging Kit |
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CASLV205PA-KIT | SBI | 1 Kit | EUR 1132 |
Cas9 Nickase: MSCV-hspCas9(D10A)-T2A-Puro SmartNickase Lentivector Plasmid + LentiStarter Packaging Kit |
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CASLV220PA-KIT | SBI | 1 Kit | EUR 1132 |
Cas9 Nickase: MSCV-hspCas9(D10A)-EF1-GFP SmartNickase Lentivector Plasmid + LentiStarter Packaging Kit |
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CASLV225PA-KIT | SBI | 1 Kit | EUR 1132 |
Multiplex gRNA Kit + Cas9 Nickase: EF1-T7-hspCas9-nickase-H1-gRNA linearized SmartNickase vector |
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CAS750A-KIT | SBI | 10 rxn | EUR 1132 |
Multiplex gRNA Kit + Cas9 Nickase: CAG-T7-hspCas9-nickase-H1-gRNA linearized SmartNickase vector |
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CAS770A-KIT | SBI | 10 rxn | EUR 1132 |
Multiplex gRNA Kit + Cas9 Nickase: CMV-T7-hspCas9-nickase-H1-gRNA linearized SmartNickase vector |
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CAS790A-KIT | SBI | 10 rxn | EUR 1132 |
Cas9 SmartNuclease Extra Ligation Kit [includes 5x ligation buffer (10 ul) and Fast ligase (2.5ul)] |
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CAS9LIG-KIT | SBI | 1 Kit | EUR 153 |
PinPoint-FC 293T Platform Kit for Targeted Gene Insertion (includes PIN320A-1, PIN200A-1, PIN510A-1 & PIN600A-1) |
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PIN320A-KIT | SBI | 1 Kit | EUR 4941 |
PinPoint-FC Murine iPSC Platform Kit for Targeted Gene Insertion (includes PIN340iPS-1, PIN200A-1, PIN510A-1 & PIN600A-1) |
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PIN340iPS-KIT | SBI | 1 Kit | EUR 4941 |
Exosome Purification and Detection Kit (Plasma) |
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abx290026-25tests | Abbexa | 25 tests | EUR 648 |
Exosome Purification and Detection Kit (Urine) |
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abx290027-25tests | Abbexa | 25 tests | EUR 648 |
Exosome Isolation kit (for serum & plasma) |
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P101 | 101Bio | - | Ask for price |
Exosome Isolation kit (for serum & plasma) |
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P101L | 101Bio | - | Ask for price |
Exosome Isolation kit (for serum & plasma) |
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P101S | 101Bio | - | Ask for price |
Exosome Isolation kit (forHuman Body Fluid) |
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P121 | 101Bio | - | Ask for price |
Exosome Isolation kit (forHuman Body Fluid) |
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P121L | 101Bio | - | Ask for price |
Exosome Isolation kit (forHuman Body Fluid) |
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P121S | 101Bio | - | Ask for price |
ExoQuick Exosome RNA Column Purification kit |
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EQ808A-1 | SBI | 20 preps | EUR 402 |
Exosome ELISA Complete Kit (CD81 detection) |
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EXOEL-CD81A-1 | SBI | 96 reactions | EUR 797 |
ExoDNAPS? Conc Exosome DNA Extraction Kit |
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K1243-20 | Biovision | EUR 827 |
ExoDNAPS? Conc Exosome DNA Extraction Kit |
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K1243-40 | Biovision | EUR 1229 |
ExoDNAUC? Conc Exosome DNA Extraction Kit |
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K1244-20 | Biovision | EUR 827 |
ExoDNAUC? Conc Exosome DNA Extraction Kit |
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K1244-40 | Biovision | EUR 1229 |
LiqBiopsy Tumor Exosome DNA Kit I |
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K1255-20 | Biovision | EUR 1001 |
LiqBiopsy Tumor Exosome DNA Kit II |
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K1256-20 | Biovision | EUR 1055 |
AAVS1 Safe Harbor Targeting Vector 2.0 - All-Purpose Donor (AAVS1-SA-puro-MCS), Complete Kit with CAS601A-1 (Cas9 SmartNuclease AAVS1-gRNA Targeting Vector) and GE640PR-1 (Junction PCR Primer Mix to confirm AAVS1 integration site) |
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GE620A-KIT | SBI | 1 kit | EUR 2132 |
AAVS1 Safe Harbor Targeting Vector 2.0 - GOI Knock-in Donor (AAVS1-SA-puro-EF1-MCS), Complete Kit with CAS601A-1 (Cas9 SmartNuclease AAVS1-gRNA Targeting Vector) and GE640PR-1 (Junction PCR Primer Mix to confirm AAVS1 integration site) |
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GE622A-KIT | SBI | 1 kit | EUR 2132 |
AAVS1 Safe Harbor Targeting Vector 2.0 - Reporter Knock-in Donor (AAVS1-SA-puro-MCS-GFP), Complete Kit with CAS601A-1 (Cas9 SmartNuclease AAVS1-gRNA Targeting Vector) and GE640PR-1 (Junction PCR Primer Mix to confirm AAVS1 integration site) |
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GE624A-KIT | SBI | 1 kit | EUR 2132 |
Chemical Defined Xeno-free Human Pluripotent Stem Cell Medium |
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abx298008-500ml | Abbexa | 500 ml | EUR 495 |
Fluorescent Exosome Standard (Urine ) |
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ESF-15 | Creative Biolabs | 100 µg | EUR 1723 |
Description: Fluorescent exosomes are labeled with green dye, which offer a stable fluorescent labeling. |
Exosome Component 5 Protein |
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20-abx260873 | Abbexa |
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Exosome Component 7 Protein |
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20-abx261347 | Abbexa |
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Exosome Component 10 Protein |
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20-abx261805 | Abbexa |
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Exosome Component 4 Protein |
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20-abx261954 | Abbexa |
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Exosome Component 9 Protein |
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20-abx262123 | Abbexa |
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Exosome Component 8 Protein |
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20-abx262850 | Abbexa |
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Exosome Component 3 Protein |
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20-abx263422 | Abbexa |
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One clarification for our findings is that we didn’t faithfully replicate His’s protocol. One other is that his protocol was incomplete. We propose that His is prone to have found and perfected infiltration embedding with paraffin wax however didn’t publish an entire protocol.